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That is an image of GLaDOS, from the game Portal (Valve). At the end of the first game, during the credits, the song "Still Alive" plays:
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Note the first line

I was tryna be clever (... again)
I presume that the swirls in the eyes means the she's being mind controlled (alternatively that she's mind controlling someone else)
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I will
not! (Just kidding... I haven't learned how to be anyone else just yet. Give it time.)